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◆ Science · Chemistry

Water is at its heaviest at 4°C — which is why ice floats

45 sec read

Almost every substance gets denser as it cools and freezes. Water cheats, and that quirk keeps ponds — and the fish in them — alive through winter.

Verified · U.S. Geological Survey

Cool a glass of water and it gets denser, right up until about 4 °C, where it reaches its maximum density of roughly 1,000 kg per cubic metre. Keep cooling, and water does something almost no other liquid does: it starts to expand again, becoming lighter as it approaches freezing.

When it finally freezes, the molecules lock into an open, hexagonal lattice held by hydrogen bonds. That cage takes up more room than liquid water, so ice is about 9% less dense — and floats.

If water behaved normally, ice would sink, and lakes would freeze solid from the bottom up.

Instead, the coldest water rises, freezes on top, and forms an insulating lid. Beneath it, liquid water survives the winter, letting fish and other life ride out the cold. A single molecular oddity — water’s density peaking above its freezing point — is one of the reasons aquatic ecosystems exist at all.

4°C
densest point
9%
ice is lighter
917
kg/m³ for ice

Sources & references

2 references

Well-established. Corroborated by 2 independent sources.

1 U.S. Geological Survey Government science agency “Pure water has a density of 1.000 g/cm³ at 4˚ C. Ice is less dense than liquid water which is why your ice cubes float in your glass.” usgs.gov ↗
2 Encyclopædia Britannica Encyclopedia “The density of cooling water will increase until the water's temperature reaches 4 °C. Then water expands and ice floats. Liquid water remains beneath the ice layer, preserving aquatic life through winter.” britannica.com ↗
✓ Last reviewed Jun 6, 2026

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