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Is glass a liquid? No — old church windows don't flow

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Is glass a liquid? No — old church windows don't flow

Medieval panes are thicker at the bottom because of how they were made. At room temperature, glass would take longer than the Universe's age to sag.

Verified · UC Riverside Physics FAQ (John Baez)

Glass is an amorphous solid, not a slow-moving liquid: at room temperature, window glass would need far longer than the age of the Universe to flow noticeably. The claim that medieval church panes are thicker at the bottom because the glass has crept downward over centuries is a myth, one repeated especially by tour guides.

Glass has no sharp freezing point. As it cools, its atoms lock rigidly in place without forming the repeating pattern of a crystal. Calling it a “supercooled liquid” persists, but many physicists regard that label as a misnomer.

Does glass flow over time?

Not measurably. In 1998, Brazilian glass scientist Edgar Zanotto calculated room-temperature flow for medieval and modern glass compositions. With P.K. Gupta he later put the relaxation time, roughly how long you would wait to see flow, at about 10²³ years. The Universe is about 10¹⁰ years old.

In 2017, Corning researchers Ozgur Gulbiten and John Mauro revisited the question using glass from Westminster Abbey dating from 1268. Medieval glass turned out to be 16 orders of magnitude less viscous than earlier estimates based on modern soda-lime glass, and still far too stiff: at most about 1 nanometre of flow in a billion years. Roman soda-lime glassware such as the Portland Vase has held its shape for nearly 2,000 years, and Stone Age obsidian arrowheads remain razor sharp, though obsidian is a tougher natural glass than window panes.

Why are old church windows thicker at the bottom?

Because of how the panes were made. Before modern float glass, panes were spun into discs (crown glass) or blown as cylinders and flattened by hand, and both methods gave sheets of varying thickness. Glaziers tended to set the heavier edge at the bottom, unaware they were starting an urban myth that would spread around the world centuries later.

~10²³ yrs
to see flow at room temperature
~1 nm
medieval glass flow per billion years
~2,000
years Roman glass has held shape

Sources & references

4 references

Well-established. Corroborated by 4 independent sources.

1 UC Riverside Physics FAQ (John Baez) academic The sheets were thicker towards the edge of the disc and were usually installed with the heavier side at the bottom. … Roman glassware provides some of the best available evidence that types of soda-lime glass are not fluid, even after nearly 2000 years. math.ucr.edu ↗
2 University of Cambridge (DoITPoMS) university teaching resource A telling point made by Zanotto and Gupta from their calculations is that the timescale over which flow might be seen at room temperature (termed the relaxation time) of 10^23 years is well beyond the age of the Universe (10^10 years). doitpoms.ac.uk ↗
3 The American Ceramic Society institution Their measurements reveal that medieval glass has a much lower viscosity than expected at room temperature—16 orders of magnitude less than previous estimates, which were based on soda-lime silicate glass. … The team’s calculations show that the medieval glass maximally flows just ~1 nm over the course of one billion years. ceramics.org ↗
4 Scientific American Science media It is an amorphous solid—a state somewhere between those two states of matter. And yet glass's liquidlike properties are not enough to explain the thicker-bottomed windows, because glass atoms move too slowly for changes to be visible. scientificamerican.com ↗
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